Cationic Polyelectrolyte

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Cationic Polyelectrolyte is a linear polymeric compound because it has a variety of lively groups affinity adsorption and many substances forming hydrogen bonds Chemical structures of two synthetic polyelectrolytes as examples To the left is poly sodium styrene sulfonate PSS and to the right is polyacrylic acid PAA Both are negatively charged polyelectrolytes when dissociated PSS is a strong polyelectrolyte fully charged in solution whereas PAA is weak partially charged. 

Cationic polyelectrolytes are polymers having positively charged moieties and anionic counterions existing on each repeating unit or in a large portion of units. The most common functional groups in these cationic polyelectrolytes include ammonium, phosphonium, and imidazolium groups.

Generally, we can see physical cross-links in these polymers that occur through electrostatic interactions. These are often known as supramolecular interactions. Typically, electrostatic interactions are not as strong as covalent bonds. However, these electrostatic interactions can enable higher thermal transitions and proper mechanical properties in comparison to non-ionic polymers.

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